I found the following users who may fit your language exchange criteria:

Username	Date	Post Link	Relevance	Offered Matches	Sought Matches
u/_lovetann	2023-03-22	Post	7	Portuguese	English, Spanish
u/swordmasterman	2023-03-25	Post	7	Portuguese	English, Spanish
u/saltytapwat3r	2023-03-30	Post	7	Portuguese (Native)	English, Spanish
u/holiday-restaurant30	2023-04-19	Post	7	Portuguese	English, Spanish
u/frokster	2023-05-01	Post	7	Portuguese	English, Spanish

Please feel free to comment on the above posts to get in contact with their authors.

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^{Hermes: a bot for r/Language_Exchange | Documentation}

I think Duolingo may be Brazilian Portuguese versus European Portuguese. As someone who currently lives in Portugal you definitely want the latter